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904L duplex stainless steel seamless pipe manufacture

Short Description:

904L stainless steel is a non-stabilized austenitic stainless steel with low carbon content. This high alloy stainless steel is added with copper to improve its resistance to strong reducing acids, such as sulphuric acid. The steel is also resistant to stress corrosion cracking and crevice corrosion. Grade 904L is non-magnetic, and offers excellent formability, toughness and weldability.
Grade 904L contains high amounts of expensive ingredients, such as molybdenum and nickel. Today, most of the applications that employ grade 904L are replaced by low-cost duplex stainless steel 2205.


Product Detail

Product Tags

Applications

▪ Wiring in electrostatic precipitators
▪ Oil refinery components
▪ Seawater cooling devices
▪ Gas scrubbing plants
▪ Pulp and paper processing industries
▪ Acetic, phosphoric and sulphuric acid proc

Grade Specification Comparison

Grade UNS No Old British Euronorm Swedish SS
BS En No Name
904L N08904 904S13 - 1.4539 X1NiCrMoCuN25-20-5 2562

Possible Alternative Grades

Grade Reasons for choosing grade 904L
316L A lower cost alternative, but with much lower corrosion resistance.
6Mo A higher resistance to pitting and crevice corrosion is needed.
2205 A very similar corrosion resistance, with the 2205 having higher mechanical strength, and at a lower cost to 904L. (2205 not suitable for temperatures above 300°C.)
Super duplex Higher corrosion resistance is needed, together with a higher strength than 904L.

Chemical Composition

Grade C Mn Si P S Cr Mo Ni Cu
904L max. 0.02 2 1 0.045 0.035 19-23 4-5 23-28 1-2

Corrosion Resistance

Grade 904L stainless steels have excellent resistance to warm seawater and chloride attack. The high resistance of grade 904L against stress corrosion cracking is due to the presence of high amounts of nickel in its composition. Moreover, the addition of copper to these grades develops resistance to sulphuric acid and other reducing agents in both aggressive and mild conditions.
The corrosion resistance of grade 904L is intermediate between super austenitic grades, with 6% molybdenum content, and standard 316L austenitic grades. Grade 904L is less resistant to nitric acid than grades 304L and 310L, which are free of molybdenum. This steel grade needs to be solution treated following cold working, to achieve maximum stress corrosion cracking resistance under critical environments.

Heat Resistance

Grade 904L stainless steels offer good oxidation resistance. However, the structural stability of this grade collapses at high temperatures, particularly above 400°C.

Heat Treatment

Grade 904L stainless steels can be solution heat-treated at 1090 to 1175°C, following by rapid cooling. Thermal treatment is suitable for hardening these grades.

Welding

Welding of grade 904L stainless steels can be performed using all conventional methods. This grade does not require pre-heat and post-weld heat treatments. Grade 904L can be subjected to hot cracking in constrained weldment. Grade 904L electrodes and rods are used for welding grade 904L steels according to AS 1554.6.

Fabrication

Grade 904L stainless steels are high purity steels with low sulphur content. They can be machined using any standard methods. These grades can be readily bent to a small radius under cold conditions. Although subsequent annealing is not required in most cases, it should be carried out when the fabrication is performed under severe stress corrosion cracking conditions.

Mechanical Properties

Tensile strength Rm 650 - 850 MPa
Yield point Rp0.2 ≥ 300 MPa
Hardness ≤ 260 HB
Elongation ≥ 35%
Modulus of elasticity, E 195 GPa
Thermal conductivity λ 14  W ⋅ m⁻¹ K⁻¹
Heat capacity cp20℃ 500 J ⋅ ​kg⁻¹ K⁻¹
Densityρ 8.10 kg/dm³
Annealing 1050 - 1150℃

Corrosion Resistance

The high content of alloying elements gives Ultra exceptionally good resistance to uniform corrosion. It can withstand a wide range of acids due to the high alloying content of chromium and molybdenum. Resistance to pitting and crevice corrosion is determined mainly by the chromium, molybdenum, and nitrogen content.It has high amounts of these elements and is suitable for demanding environments like chlorinated sea water. Resistance to stress corrosion cracking increases with increased content of nickel and molybdenum in particular. This means that Ultra has very good resistance to stress corrosion cracking.
Welding:
Welding of stainless steel grade requires filler material without which it results in poor strength properties. Filler metals such as AWS A5.14 ERNiCrMo-3, and alloy 625 are recommended. Electrodes used in the process, have to match with AWS A5.11 ENiCrMo-12.
Heat treatment:
Forging, upsetting and other operations relating to this material can be performed at 982 - 1149°C (1800 - 2100°F). It is recommended that temperatures do not exceed this range as it would result in scaling and reduction in the workability of the material. To re-attain maximum corrosion resistant properties, it is advisable to perform post-process annealing.
Stainless steel grade does not respond to heat treatment. Hardening is possible only through cold reduction.

Available Sizes And Specifications

904L stainless steel plate sizes and specifications
Grade 904L
Cold rolled stainless steel plate Thickness: 0.3mm- 16.0mm, Width: 1000mm - 2000mm,
Length: as requirements, Surface: 2B/BA/SB/8K/HL/1D/2D etc
Hot rolled stainless steel sheet Thickness: 3.0mm - 300mm, Width: 1000mm - 3000mm
Length: as requirements, Surface: No.1/pickling
Standard ASTM A240/A480, ASTM B688, ASTM B463/SB463, ASTM B168/SB168, ASTM B443/SB443/B424/SB424B625/SB625 B575/SB575, JIS G4303,
BS 1449, DN17441, G4305
Stainless steel plate Thickness: 8.0mm - 300mm, Width: 1000mm - 3000mm
Length: as requirements, Surface: No.1/pickling
904L stainless steel strip sizes and specifications
Grade 904L
Cold rolled stainless steel strip Thickness: 0.3mm- 3.0mm, Width: 5mm - 900mm,
Surface: 2B/BA/SB/8K/HL/1D/2D etc
Hot rolled stainless steel strip Thickness: 3.0mm - 16mm, Width: 10mm - 900mm
Surface: No.1/pickling
Stainless steel foil Thickness: 0.02mm- 0.2mm, Width: Less than 600mm, Surface: 2B
Standard ASTM A240/A480, ASTM B688, ASTM B463/SB463, ASTM B168/SB168, ASTM B443/SB443/B424/SB424B625/SB625 B575/SB575, JIS G4303,  BS 1449, DN17441, G4305
904L stainless steel coil sizes and specifications
Grade 904L
Cold rolled stainless steel coil Thickness: 0.3mm- 3.0mm, Width: 1000mm - 2000mm,
Surface: 2B/BA/SB/8K/HL/1D/2D etc
Hot rolled stainless steel coil Thickness: 3.0mm - 16mm, Width: 1000mm - 2000mm
Surface: No.1/pickling
Standard ASTM A240/A480, ASTM B688, ASTM B463/SB463, ASTM B168/SB168, ASTM B443/SB443/B424/SB424B625/SB625 B575/SB575, JIS G4303,   BS 1449, DN17441, G4305
904L stainless steel pipe sizes and specifications
Grade 904L
Stainless steel seamless pipe Outside diameter: 4.0 - 1219mm, Thickness: 0.5 -100mm,
Length: 24000mm
Stainless steel welded pipe Outside diameter: 6.0 - 2800mm, Thickness: 0.3 -45mm,
Length: 18000mm
 Stainless steel capillary pipe Outside diameter: 0.4 - 16.0mm, Thickness: 0.1 -2.0mm,
Length: 18000mm
Stainless steel welded sanitary pipe Outside diameter:8.0- 850mm, Thickness: 1.0 -6.0mm
Stainless steel seamless sanitary pipe Outside diameter: 6.0- 219mm, Thickness: 1.0 -6.0mm
Stainless steel square pipe Side Length: 4*4 - 300*300mm, Thickness: 0.25 - 8.0mm, Length: 18000mm
Stainless steel rectangular pipe Side Length: 4*6 - 200*400mm, Thickness: 0.25 - 8.0mm, Length: 18000mm
Stainless steel coil pipe Outside diameter: 0.4 - 16mm, Thickness: 0.1 - 2.11mm
Standard American Standard: ASTM A312, ASME SA269, ASTM A269, ASME SA213, ASTM A213 ASTM A511 ASTM A789, ASTM A790, ASTM A376, ASME SA335, B161, SB163, SB338, SB667/668
Germany Standard: DIN2462.1-1981, DIN17456-85, DIN17458-85·
European Standard: EN10216-5, EN10216-2
Japanese Standard: JIS G3463-2006, JISG3459-2012
Russian Standard: GOST 9941-81
904L stainless steel profile sizes and specifications
Grade 904L
Specification EN, DIN, JIS, ASTM, BS, ASME, AISI, ISO
Standard ASTM A276/ASME SA276, ASTM A479/ASME SA479 & ASTM A164/ASME SA164 .
Stainless steel round Bar Diameter: 2mm - 600mm
Stainless steel bright Bar Diameter: 2mm - 600mm
Stainless steel hex Bar Dimension: 6mm - 80mm
Stainless steel square bar Dimension: 3.0 - 180mm
Stainless steel flat bar Thickness: 0.5mm - 200mm, Width: 1.5mm - 250 mm
Stainless steel angle bar as requirements
Length Normally 6m, or produce as requirements
Surface Black, Bright. Peeled and Polished, Solution annealed.
Delivery condition cold drawn, hot rolled, forged, grinding, centerless grinding
Tolerance H8, H9, H10, H11, H12, H13,K9, K10, K11, K12 or as per clients’ requirements

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